Exploring a New Structure Family: Alkali Borosulfates Na\\r sub/5sub\\r [B(SO\\r sub/4sub\\r )\\r sub/4sub\\r ], A\\r sub/3sub\\r [B(SO\\r sub/4sub\\r )\\r sub/3sub\\r ] (A = K, Rb), Li[B(SO\\r sub/4sub\\r )\\r sub/2sub\\r ], and Li[B(S\\r sub/2sub\\r O\\r sub/7sub\\r )\\r sub/2sub\\r ]