An Unusual Alkyltrihydroaluminate. Crystal Structures of [AlH\\r <sub/>2sub>\\r {C(SiMe\\r <sub/>3sub>\\r )\\r <sub/>2sub>\\r (SiMe\\r <sub/>2sub>\\r OMe)}(μ-H)Li(THF)], [AlCl\\r <sub/>2sub>\\r {C(SiMe\\r <sub/>2sub>\\r OMe)(SiMe\\r <sub/>3sub>\\r )\\r <sub/>2sub>\\r (THF)], and [Li{C(SiMe\\r <sub/>2sub>\\r OMe)(SiMe\\r <sub/>3sub>\\r )\\r <sub/>2sub>\\r }(THF)\\r <sub/>2sub>\\r ] (THF = Tetrahydrofuran)

Synthesis of Mixed-Valence Platinum Triangulo Clusters [Pt\\r <sub/>3sub>\\r (μ-PPh\\r <sub/>2sub>\\r )\\r <sub/>2sub>\\r (μ-C\\r <sub/>6sub>\\r F\\r <sub/>5sub>\\r )(C\\r <sub/>6sub>\\r F\\r <sub/>5sub>\\r )(PPh\\r <sub/>2sub>\\r R)\\r <sub/>2sub>\\r ] (R = Ph, Me, Et). Crystal Structures of [Pt\\r <sub/>3sub>\\r (μ-PPh\\r <sub/>2sub>\\r )\\r <sub/>2sub>\\r (μ-C\\r <sub/>6sub>\\r F\\r <sub/>5sub>\\r )(C\\r <sub/>6sub>\\r F\\r <sub/>5sub>\\r )(PPh\\r <sub/>3sub>\\r )\\r <sub/>2sub>\\r ] and [Pt\\r <sub/>3sub>\\r (μ-AgOClO\\r <sub/>3sub>\\r )(μ-PPh\\r <sub/>2sub>\\r )\\r <sub/>2sub>\\r (μ-C\\r <sub/>6sub>\\r F\\r <sub/>5sub>\\r )(C\\r <sub/>6sub>\\r F\\r <sub/>5sub>\\r )(PPh\\r <sub/>3sub>\\r )\\r <sub/>2sub>\\r ]\\r ^†

Synthesis and Characterization of Substituted (Thiomethyl)lithium Compounds. Structures of [{Li(CH\\r <sub/>2sub>\\r SMe)(THF)}\\r <sub/>∞sub>\\r ] and [Li\\r <sub/>2sub>\\r (CH\\r <sub/>2sub>\\r SPh)\\r <sub/>2sub>\\r (THF)\\r <sub/>4sub>\\r ]

1:1 and 2:1 Lithium Zincates with Intramolecular Coordination. Structures of Li(thf)Zn(C\\r <sub/>6sub>\\r H\\r <sub/>4sub>\\r CH\\r <sub/>2sub>\\r NMe\\r <sub/>2sub>\\r -2)\\r <sub/>3sub>\\r and Li\\r <sub/>2sub>\\r Zn(C\\r <sub/>6sub>\\r H\\r <sub/>4sub>\\r CH\\r <sub/>2sub>\\r NMe\\r <sub/>2sub>\\r -2)\\r <sub/>4sub>

Synthesis and Structures of [((Me\\r <sub/>3sub>\\r Si)\\r <sub/>3sub>\\r CAlF\\r <sub/>2sub>\\r )\\r <sub/>2sub>\\r (\\r μ\\r -O)Li\\r <sub/>2sub>\\r (THF)\\r <sub/>4sub>\\r ] and [{Li(Me\\r <sub/>3sub>\\r Si)\\r <sub/>3sub>\\r CAlF\\r <sub/>3sub>\\r (THF)}\\r <sub/>3sub>\\r LiF(THF)]

Die Kristallstrukturen von (PPh\\r <sub/>4sub>\\r )\\r <sub/>2sub>\\r RuCl\\r <sub/>6sub>\\r ·2 CH\\r <sub/>2sub>\\r Cl2, (AsPh\\r <sub/>4sub>\\r )\\r <sub/>2sub>\\r OsCl\\r <sub/>6sub>\\r ·2 CH\\r <sub/>2sub>\\r Cl\\r <sub/>2sub>\\r und\\r β\\r -(PPh\\r <sub/>4sub>\\r )\\r <sub/>2sub>\\r UCl\\r <sub/>6sub>\\r ·2 CH\\r <sub/>2sub>\\r Cl\\r <sub/>2sub>

Polynuclear Aggregation of Manganese Dichloride. Syntheses, Properties, and Structures of Polymeric [MnCl\\r <sub/>2sub>\\r (THF)\\r <sub/>1.6sub>\\r ]\\r <sub/>∞sub>\\r , Dimeric [(THF)\\r <sub/>4sub>\\r Mg(μ-Cl)\\r <sub/>2sub>\\r MnCl\\r <sub/>2sub>\\r ], and Ionic [Mg(H\\r <sub/>2sub>\\r O)\\r <sub/>2sub>\\r (THF)\\r <sub/>4sub>\\r ][Mg(H\\r <sub/>2sub>\\r O)\\r <sub/>4sub>\\r (THF)\\r <sub/>2sub>\\r ][MnCl\\r <sub/>4sub>\\r ]\\r <sub/>2sub>\\r ·2THF Compounds

Gold(I) Complexes with the\\r nido\\r -Diphosphino Ligand [7,8-(Ph\\r <sub/>2sub>\\r P)\\r <sub/>2sub>\\r -7,8-C\\r <sub/>2sub>\\r B\\r <sub/>9sub>\\r H\\r <sub/>10sub>\\r ]\\r ^-\\r . Preparation of the First Metallocarborane Complex of this Ligand. Crystal Structures of [Au{(PPh\\r <sub/>2sub>\\r )\\r <sub/>2sub>\\r C\\r <sub/>2sub>\\r B\\r <sub/>9sub>\\r H\\r <sub/>10sub>\\r }(PPh\\r <sub/>3sub>\\r )]·CH\\r <sub/>2sub>\\r Cl\\r <sub/>2sub>\\r and [Au\\r <sub/>2sub>\\r {(PPh\\r <sub/>2sub>\\r )\\r <sub/>2sub>\\r C\\r <sub/>2sub>\\r B\\r <sub/>9sub>\\r H\\r <sub/>10sub>\\r }\\r <sub/>2sub>\\r {(PPh\\r <sub/>2sub>\\r )\\r <sub/>2sub>\\r (CH\\r <sub/>2sub>\\r )\\r <sub/>3sub>\\r }]·3Me\\r <sub/>2sub>\\r CO

Two binuclear molecular magnets: K\\r <sub/>2sub>\\r Fe\\r <sub/>2sub>\\r (C\\r <sub/>2sub>\\r O\\r <sub/>4sub>\\r )Cl\\r <sub/>6sub>\\r (H\\r <sub/>2sub>\\r O)\\r <sub/>2sub>\\r and K\\r <sub/>6sub>\\r Fe\\r <sub/>6sub>\\r (C\\r <sub/>2sub>\\r O\\r <sub/>4sub>\\r )\\r <sub/>3sub>\\r Cl\\r <sub/>14sub>\\r (H\\r <sub/>2sub>\\r O)\\r <sub/>10sub>

Syntheses, X-ray Structural Characterizations, and Thermal Stabilities of Two Nonclassical Trinuclear Vanadium(IV) Complexes, (V\\r <sub/>3sub>\\r (μ\\r <sub/>3sub>\\r -O)O\\r <sub/>2sub>\\r )(μ\\r <sub/>2sub>\\r -O\\r <sub/>2sub>\\r P(CH\\r <sub/>2sub>\\r C\\r <sub/>6sub>\\r H\\r <sub/>5sub>\\r )\\r <sub/>2sub>\\r )\\r <sub/>6sub>\\r (H\\r <sub/>2sub>\\r O) and (V\\r <sub/>3sub>\\r (μ\\r <sub/>3sub>\\r -O)O\\r <sub/>2sub>\\r )(μ\\r <sub/>2sub>\\r -O\\r <sub/>2sub>\\r P(CH\\r <sub/>2sub>\\r C\\r <sub/>6sub>\\r H\\r <sub/>5sub>\\r )\\r <sub/>2sub>\\r )\\r <sub/>6sub>\\r (py), and Polymeric Complexes of Stoichiometry (VO(O\\r <sub/>2sub>\\r PR\\r <sub/>2sub>\\r )\\r <sub/>2sub>\\r )\\r <sub/>∞sub>\\r , R\\r <sub/>2sub>\\r = Ph\\r <sub/>2sub>\\r and\\r o-\\r (CH\\r <sub/>2sub>\\r )\\r <sub/>2sub>\\r (C\\r <sub/>6sub>\\r H\\r <sub/>4sub>\\r )