Substitution of [Ru\\r sub/10sub\\r C\\r sub/2sub\\r (CO)\\r sub/24sub\\r ]\\r sup2supsup-sup\\r with Allene. Reversible Formation of [Ru\\r sub/10sub\\r C\\r sub/2sub\\r (CO)\\r sub/22sub\\r (μ-η\\r sup2sup\\r :η\\r sup2sup\\r -C\\r sub/3sub\\r H\\r sub/4sub\\r )]\\r sup2supsup-sup\\r and [Ru\\r sub/10sub\\r C\\r sub/2sub\\r (CO)\\r sub/20sub\\r (μ-η\\r sup2sup\\r :η\\r sup2sup\\r -C\\r sub/3sub\\r H\\r sub/4sub\\r )\\r sub/2sub\\r ]\\r sup2supsup-sup

Synthesis and Characterization of η\\r sup2sup\\r -C\\r sub/60sub\\r and μ\\r sub/3sub\\r -η\\r sup2sup\\r ,η\\r sup2sup\\r ,η\\r sup2sup\\r -C\\r sub/60sub\\r Triosmium Cluster Complexes

Polynuclear Magnesium and Magnesium−Titanium Species. Syntheses and Crystal Structures of [Mg\\r sub/4sub\\r (μ\\r sub/3sub\\r ,η\\r sup2sup\\r -ddbfo)\\r sub/2sub\\r (μ,η\\r sup2sup\\r -ddbfo)\\r sub/2sub\\r (μ,η\\r sup1sup\\r -ddbfo)\\r sub/2sub\\r (η\\r sup1sup\\r -ddbfo)\\r sub/2sub\\r ], [Mg\\r sub/4sub\\r (μ\\r sub/3sub\\r -OMe)\\r sub/2sub\\r (μ,η\\r sup2sup\\r -ddbfo)\\r sub/2sub\\r (μ,η\\r sup1sup\\r -ddbfo)\\r sub/2sub\\r (η\\r sup1sup\\r -ddbfo)\\r sub/2sub\\r (CH\\r sub/3sub\\r OH)\\r sub/5sub\\r ], and [Mg\\r sub/4sub\\r (μ\\r sub/3sub\\r ,η\\r sup2sup\\r -thffo)\\r sub/2sub\\r (μ,η\\r sup2sup\\r -thffo)\\r sub/2sub\\r (μ,η\\r sup1sup\\r -thffo)\\r sub/2sub\\r {μ-OTi(DIPP)\\r sub/3sub\\r }\\r sub/2sub\\r ] Aggregates

Nucleophilic Addition of Alcohols to [Fe\\r sub/2sub\\r (CO)\\r sub/6sub\\r (μ-PPh\\r sub/2sub\\r ){μ-η\\r sup1sup\\r :η\\r sup2supsub/αβsub\\r -(R)C\\r sub/αsub\\r C\\r sub/βsub\\r C\\r sub/γsub\\r H\\r sub/2sub\\r }] (R = H, Ph):  Generation of the Binuclear β,γ-Unsaturated Esters [Fe\\r sub/2sub\\r (CO)\\r sub/5sub\\r (μ-PPh\\r sub/2sub\\r )(μ-η\\r sup1sup\\r (O):η\\r sup1sup\\r (C):η\\r sup2sup\\r (C)-{R\\r sup1sup\\r O(O)CCH\\r sub/2sub\\r }CCH\\r sub/2sub\\r )] (R\\r sup1sup\\r = Me, Et,\\r supisup\\r Pr)

Gas Phase Study of the Clustering Reactions of C\\r sub/2sub\\r H\\r sub/5subsup+sup\\r ,\\r isi\\r -C\\r sub/3sub\\r H\\r sub/7subsup+sup\\r , and\\r iti\\r -C\\r sub/4sub\\r H\\r sub/9subsup+sup\\r with CO\\r sub/2sub\\r and N\\r sub/2sub\\r O:  Isomeric Structure of C\\r sub/2sub\\r H\\r sub/5subsup+sup\\r , C\\r sub/2sub\\r H\\r sub/5subsup+sup\\r (CO\\r sub/2sub\\r )\\r i\\r sub/nsubi\\r , and C\\r sub/2sub\\r H\\r sub/5subsup+sup\\r (N\\r sub/2sub\\r O)\\r i\\r sub/nsubi

Synthesis, Structure, and Properties of {(\\r suptsup\\r Bu\\r sub/2sub\\r PC\\r sub/2sub\\r H\\r sub/4sub\\r P\\r suptsup\\r Bu\\r sub/2sub\\r )Ni}\\r sub/2sub\\r (μ-η\\r sup2sup\\r :η\\r sup2sup\\r -C\\r sub/6sub\\r H\\r sub/6sub\\r ) and (\\r suptsup\\r Bu\\r sub/2sub\\r PC\\r sub/2sub\\r H\\r sub/4sub\\r P\\r suptsup\\r Bu\\r sub/2sub\\r )Ni(η\\r sup2sup\\r -C\\r sub/6sub\\r F\\r sub/6sub\\r )\\r sup1sup

Ru\\r sub/3sub\\r (CO)\\r sub/9sub\\r (μ\\r sub/3sub\\r -η\\r sup2sup\\r ,η\\r sup2sup\\r ,η\\r sup2sup\\r -C\\r sub/60sub\\r ):  A Cluster Face-Capping, Arene-Like Complex of C\\r sub/60sub

Polycarbon ligands: synthesis and characterization of the phosphinodiynes Ph\\r sub/2sub\\r PC≡C-C≡CR (R = Bu\\r supiti\\r sup\\r , Ph, SiMe\\r sub/3sub\\r ), the μ-η\\r sup1sup\\r ,η\\r sup2supsub/α,βsub\\r -butadiynyl complexes Ru\\r sub/2sub\\r (CO)\\r sub/6sub\\r -(μ-PPh\\r sub/2sub\\r )(μ-η\\r sup1sup\\r ,η\\r sup2supsub/α,βsub\\r -C≡C-C≡CR), and the molecular structure of a cobalt carbonyl derivative Ru\\r sub/2sub\\r (CO)\\r sub/6sub\\r (μ-PPh\\r sub/2sub\\r )(μ-η\\r sup1sup\\r ,η\\r sup2supsub/α,βsub\\r :-μ-η\\r sup2sup\\r ,η\\r sup2supsub/γ,δsub\\r -C≡C-C≡CBu\\r supiti\\r sup\\r )Co\\r sub/2sub\\r (CO)\\r sub/6sub

Stability and Bonding Situation of Electron-Deficient Transition-Metal Complexes. Theoretical Study of the CO-Labilizing Effect of Ligands L in [W(CO)\\r sub/5sub\\r L] (L = C\\r sub/2sub\\r H\\r sub/2sub\\r , NCH, N\\r sub/2sub\\r , C\\r sub/2sub\\r H\\r sub/4sub\\r , OH\\r sub/2sub\\r , SH\\r sub/2sub\\r , NH\\r sub/3sub\\r , F\\r sup-sup\\r , Cl\\r sup-sup\\r , OH\\r sup-sup\\r , SH\\r sup-sup\\r ) and [W(CO)\\r sub/4sub\\r L]\\r sup2supsup-sup\\r (L\\r sup2supsup-sup\\r = O\\r sub/2sub\\r C\\r sub/2sub\\r H\\r sub/2subsup2supsup-sup\\r , S\\r sub/2sub\\r C\\r sub/2sub\\r H\\r sub/2subsup2supsup-sup\\r ) and the Structure of the 16-Valence-Electron Complexes [W(CO)\\r sub/4sub\\r L] and [W(CO)\\r sub/3sub\\r L]\\r sup2-sup\\r  \\r sup†sup

Structure of an I\\r sup-sup\\r ·(H\\r sub/2sub\\r O)\\r sub/6sub\\r Anion Cluster in a 3D Anion Crystal Host [I·(H\\r sub/2sub\\r O)\\r sub/6sub\\r Fe(CN)\\r sub/6sub\\r ·H\\r sub/2sub\\r O]\\r sup4supsup-sup